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The technique works on the fact that bonds and groups of bonds vibrate at characteristic frequencies. A molecule that is exposed to infrared rays absorbs infrared energy at frequencies which are characteristic to that molecule. During FTIR analysis, a spot on the specimen is subjected to a modulated IR beam. The specimen's transmittance and reflectance of the infrared rays at different frequencies is translated into an IR absorption plot consisting of reverse peaks. The resulting FTIR spectral pattern is then analyzed and matched with known signatures of identified materials in the FTIR library.


Single fibers or particles are sufficient enough for material identification through FTIR analysis. Organic contaminants in solvents may also be analyzed by first separating the mixture into its components by gas chromatography, and then analyzing each component by FTIR.
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